Investigation of self-propagating high-temperature synthesis based on TiB+Ti composite powders
DOI:
https://doi.org/10.51301/ejsu.2025.i1.03Keywords:
composite powder, titanium boride, titanium, electron-beam coatings, powder surfacing, self-propagating high-temperature synthesisAbstract
This article considers modern methods of increasing wear resistance and reliability of machine parts using composite materials, especially in the field of powder surfacing and synthesis of metal-matric composites. One of the effective methods is self-propagating high-temperature synthesis (SHS), which allows obtaining composite coatings with improved mechanical and thermal properties. Powder surfacing methods, such as electron beam surfacing (EBF), provide wear-resistant, heat-resistant and hardening coatings on a titanium base. Powders of titanium and its alloys are obtained by reduction of oxides with calcium hydride, which contributes to the formation of materials with high strength and good flowability. Special attention is paid to titanium boride as a strengthening phase for composites. The use of these technologies contributes to a significant increase in the durability and reliability of machines and mechanisms, which leads to resource saving and reduction of operating costs. The studies include the analysis of structural characteristics of the obtained powders and coatings, as well as the determination of their physical and mechanical properties. The variations in these properties as a function of the titanium binder content in the composite powder are analyzed. The description of the microstructure of powders and coatings, as well as the influence of composition on their characteristics, allows us to draw conclusions about the possibility of using these materials to create functional coatings with improved performance characteristics, such as increased wear resistance and heat resistance. The results of the study can be useful for the development of new materials with improved operational properties for use in various industries.
References
Korosteleva, E.N. & Korzhova, V.V. (2020). Structure and phase composition of metal-matrix composites (TiB) – Ti ob-tained by SHS and vacuum sintering. Russian Physics Journal, (63), 1195-1201. https://doi.org/10.1007/s11182-020-02159-4
Liang, Y.H., Wang, H.Y., Yang, Y.F., Zhao, R.Y. & Jiang, Q.C. (2008). Effect of Cu content on the reaction behaviors of self-propagating high-temperature synthesis in Cu–Ti–B₄C sys-tem. Journal of Alloys and Compounds, 462(1–2), 113-118. https://doi.org/10.1016/j.jallcom.2007.08.033
Zhang, L., Wang, H.Y., Li, S.T., Liu, C. & Jiang, Q.C. (2009). Influence of reactant particle size on products of self-propagating high-temperature synthesis in 30 wt.% Cr–Ti–B₄C system. Journal of Alloys and Compounds, 468(1–2), 143-149. https://doi.org/10.1016/j.jallcom.2008.01.007
Levashov, E.A., Mukasyan, A.S., Rogachev, A.S. & Shtansky, D.V. (2016). Self-propagating high-temperature synthesis of modern materials and coatings. International Materials Reviews, 62(4), 203–239. https://doi.org/10.1080/09506608.2016.1243291
Sahay, S.S., Ravi Chandran, K.S. & Atri, R. (1999). Evolution of microstructure and phases in situ processed Ti–TiB compo-sites containing high volume fractions of TiB whiskers. Journal of Materials Research, (14), 4214–4223.
Panin, V.E., Belyuk, S.I., Durakov, V.G., Pribytkov, G.A. & Rempe, N.G. (2000). Electron beam surfacing in vacuum: equipment, technology, and coating properties. Welding Produc-tion, (2), 34–38. https://doi.org/10.1080/09507110009549234
Panin, V.E., Durakov, V.G., Pribytkov, G.A., Polev, I.V. & Belyuk, S.I. (1998). Electron beam surfacing of powder carbide steels. Physics and Chemistry of Material Processing, (6), 53–59
Chandran, K.S.R., Panda, K.B. & Sahay, S.S. (2004). TiBw-reinforced Ti composites: Processing, properties, application prospects, and research needs. JOM, (56), 42–48. https://doi.org/10.1007/s11837-004-0127-1
Saito, T. (2004). The automotive application of discontinuously reinforced TiB–Ti composites. JOM, (56), 33–36. https://doi.org/10.1007/s11837-004-0125-3
Huang, L.J., Geng, L., Peng, H.X. & Zhang, J. (2011). Room temperature tensile fracture characteristics of in situ TiBw/Ti6Al4V composites with a quasi-continuous network ar-chitecture. Scripta Materialia, 64(9), 844–847. https://doi.org/10.1016/j.scriptamat.2011.01.011
Novikov, N.P., Borovinskaya, I.P. & Merzhanov, A.G. (1974). Dependence of the composition of products and combustion speed in metal-boron systems on the ratio of reactants. Combus-tion and Explosion Physics, 10(2), 201–206 https://doi.org/10.1007/BF01464173
Azatyan, T.S. & Maltsev, V.M. (1980). On the mechanism of combustion wave propagation in titanium-boron mixtures. Com-bustion and Explosion Physics, 16(2), 37–42. https://doi.org/10.1007/BF00740195
Attar, H., Lober, L., Funk, A., et al. (2015). Mechanical behav-ior of porous commercially pure Ti and Ti-TiB composite mate-rials manufactured by selective laser melting. Materials Science & Engineering A, (625), 350-356. https://doi.org/10.1016/j.msea.2014.12.036
Moissan, A. (1895). Comptes Rendus, 70, 290. Crochard (Pa-rís)
Moissan, A. (1896). Préparation et propriétés du titane. Annales de Chimie et de Physique, (7), 229
Wedekind, E. (1913). Synthese von Boriden im elektrischen Vakuumofen. Berichte der Deutschen Chemischen Gesellschaft, (46), 1198. https://doi.org/10.1002/cber.191304601155
Kusakina, Ju., Levashov, E., Livanov, D. & Karabasov, Ju. (2002). New Materials. MISiS, Moscow
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