Development of the coagulant obtaining technology from substandard bauxite of Kazakhstan for wastewater treatment
DOI:
https://doi.org/10.51301/ejsu.2025.i2.04Keywords:
bauxite, technology, coagulant, flocculant, water treatment, particle size distributionAbstract
One of the important environmental problems of Kazakhstan is the insufficient quality of natural and wastewater treatment, the reason for which is the lack of the main, mandatory reagent in water purification technology – coagulant. Aluminum-containing natural and man-made raw materials can be comprehensively processed in order to obtain modified mixed reagents-coagulants. One of the promising types of raw materials on the territory of Kazakhstan for the production of coagulants are substandard bauxites of the Krasnooktyabrsky deposit. This article presents a fundamentally new approach to the development of a technology for producing an effective coagulant with high coagulating properties in a wide pH range – a mixed sulfate aluminum-iron-silica coagulant (MSAISC) – when decomposing Red October bauxite with sulfuric acid with maximum extraction of aluminum, iron and silicon into a paste-like phase. Such a composition of the coagulant, called by us MSAISC (mixed sulfate aluminum-iron-silica coagulant) allows you to expand the range of action both in temperature and pH of the medium. In this sense, silicon coagulant, as well as modern aluminum polyoxychlorides, can be used without flocculant. The simultaneous presence of aluminum, iron and silicon salts in the composition of the coagulant makes it possible to combine the properties of «three in one».
References
Teh, C.Y., Budiman, P.M., Shak, K.P.Y. & Wu, T.Y. (2016). Recent advancement of coagulation-flocculation and its application in wastewater treatment. Industrial & Engineering Chemistry Research, 55(16), 4363-4389. https://doi.org/10.1021/ACS.IECR.5B04703
Kingsley, O.I. (2019). Prospects and Challenges of Using Coagulation-Flocculation Method in the Treatment of Effluents, Advanced Journal of Chemistry, section A, 2(2), 105-127. https://doi.org/10.29088/SAMI/AJCA.2019.2.105127
Zubkova, O.S., Alekseev, A.I. & Zalilova. M.M. (2020). Research of Combined Use of Carbon and Aluminum Compounds for Wastewater Treatment. Izvestiya Vysshikh Uchebnykh Zavedenii, Seriya Khimiya i Khimicheskaya Tekhnologiya, 63(4), 86-91. https://doi.org/10.6060/ivkkt.20206304.6131
Dotto, J., Fagundes-Klen, M.R., Veit, M.T., Palácio, S.M. & Bergamasco, R. (2019). Performance of different coagulants in the coagulation/flocculation process of textile wastewater. Journal of Cleaner Production, (208), 656-665. https://doi.org/10.1016/j.jclepro.2018.10.112
Gan, Y., Li, J., Zhang, L., Wu, B., Huang, W., Li, H. & Zhang, S. (2021). Potential of titanium coagulants for water and wastewater treatment: Current status and future perspectives. Chemical Engineering Journal, (406), 126837. https://doi.org/10.1016/j.cej.2020.126837
Zhuang, J., Qi, Y., Yang, H., Li, H. & Shi, T. (2021). Preparation of polyaluminum zirconium silicate coagulant and its performance in water treatment. Journal of Water Process Engineering, (41), 102023. https://doi.org/10.1016/j.jwpe.2021.102023
Matveeva, V.A., Chukaeva, M.A. & Semenova, A.I. (2024). Iron ore tailings as a raw material for Fe-Al coagulant production. Journal of Mining Institute, (267), 433-443. https://pmi.spmi.ru/pmi/article/view/16474
Almeida, V.O., Schneider, I.A.H. (2020). Production of a ferric chloride coagulant by leaching an iron ore tailing. Minerals Engineering, (156), (106511). https://doi.org/10.1016/j.mineng.2020.106511
Naumov, K.I., Shvedov, I.M. & Maloletnev, A.S. (2014). Application of New Technologies for Producing Coagulant (Aluminum Sulfate) from Coal Waste. Mining Information and Analytical Bulletin, (5), 67-72.
Musina, U.Sh., Nureyev, S.S. & Kurbanova, L.S. (2007). Investigation of the process of obtaining a titanium-modified mixed sulfate coagulant from Krasnoktyabrsky bauxite. Bulletin of KazNTU named after K.I. Satpayev, (5), 137-139.
Valeev, D.V. (2015). Acid technology for the production of alumina and coagulants from Russian high-silica raw materials. II Russian Annual Conference of young researchers and postgraduates «Physico-chemistry and technology of inorganic materials».
Musina, U.Sh., Nurkeev, C.S., Kurbanova, L.S., Zharkimbaeva, G.B. & Ahmedova, G.R. (2007). Investigation of coagulating properties of a new inorganic coagulant. Hydrometeorology & Ecology, (1), 104-108.
Mondillo, N., Herrington, R. & Boni, M. (2021). Bauxite. Encyclopedia of Geology (Second Edition). https://doi.org/10.1016/B978-0-08-102908-4.00046-1
National Minerals Information Center. (2017). Bauxite and Alumina Statistics and Information. Retrieved from: https://minerals.usgs.gov/minerals/pubs/commodity/bauxite/
Kenzhaliev, B.K., Kuldeev, E.I., Abdulvaleev, R.A., Pozmogov, V.A., Beisembekova, K.O., Gladyshev, S.V. & Tastanov, E.A. (2017). Prospects for the development of the aluminum industry in Kazakhstan. News of the Academy of Sciences of the Republic of Kazakhstan. Series of Geology and Technical Sciences, 3(423), 151-160.
Bekturganov, N.S., Abisheva, Z.S., Abdulvaliev, R.A., Tastanov, E.A., Ahmedov, S.N., Medvedev, V.V. & Gladyshev, S.V. (2015). Perspektivy rasshireniya syr'evoj bazy alyuminievoj promyshlennosti Kazahstana. Resursosberegayushchie tekhnologii v obogashchenii rud i metallurgii cvetnyh metallov», Almaty
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 Engineering Journal of Satbayev University

This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
<div class="pkpfooter-son">
<a rel="license" href="http://creativecommons.org/licenses/by-nc/4.0/"><img alt="Creative Commons License" style="border-width:0" src="https://i.creativecommons.org/l/by-nc/4.0/80x15.png"></a><br>This work is licensed under a <a rel="license" href="http://creativecommons.org/licenses/by-nc/4.0/">Creative Commons Attribution-NonCommercial 4.0 International License</a>.
</div>